A lot has to do with pattern and color so it really depends. Over 1-3/16" with a decent pattern would be of interest...majority of large slags I've seen are that size or smaller. Of course there are bigger slags out there...
The whole industrial application is an interesting topic. Industry usually tries to save money by doing without excess so I'd expect the ones made for industrial applications to be made from the plainest glass possible (ie: those transparent green marbles used for fiberglass or something) Back in the day where things were at the onset of industrial revolution it would make sense that large slags would be used for industrial applications, cause hey - they're already in the business of making marbles and if there's an order to fill for some larger marbles other than "toys", why not?